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TEMPERATURE PRESSURE RELATIONSHIP
of refrigerants 12 and 22.

The figures in BOLD/ITALICS
are measurements of vacuum in inches of mercury.
All others are in gauge measurement pounds per square inch.


CHART I
CHART II
CHART III
Temper-
ature
Refrigerant Temper-
ature
Refrigerant Temper-
ature
Refrigerant
deg. F. 12 22 deg. F. 12 22 deg. F. 12 22
-60 19.0 11.9 12 15.8 34.9 43 39.7 73.5
-55 17.3 9.1 13 16.5 35.9 44 40.7 75.0
-50 15.4 6.0 14 17.1 36.9 45 41.7 76.6
-45 13.3 2.6 15 17.7 37.9 46 42.6 78.2
-40 10.9 0.6 16 18.4 38.9 47 43.6 79.8
-35 8.3 2.7 17 19.0 40.0 48 44.6 81.4
-30 5.4 5.0 18 19.7 41.1 49 45.7 83.0
-25 2.3 7.5 19 20.4 42.2 50 46.7 84.7
-20 0.5 10.3 20 21.0 43.3 55 52.0 93.3
-18 1.3 11.5 21 21.7 44.4 60 57.7 102.5
-16 2.0 12.7 22 22.4 45.5 65 63.7 112.2
-14 2.8 13.9 23 23.2 46.7 70 70.1 122.5
-12 3.6 15.2 24 23.9 47.8 75 76.9 133.4
-10 4.4 16.6 25 24.6 49.0 80 84.1 145.0
-8 5.3 18.0 26 25.4 50.2 85 91.7 157.2
-6 6.2 19.4 27 26.1 51.5 90 99.7 170.1
-4 7.1 20.9 28 26.9 52.7 95 108.2 183.7
-2 8.1 22.5 29 27.7 54.0 100 117.1 197.9
0 9.2 24.1 30 28.5 55.2 105 126.5 212.9
1 9.7 24.9 31 29.3 56.5 110 136.4 228.7
2 10.2 25.7 32 30.1 57.8 115 146.7 245.3
3 10.7 26.6 33 30.9 59.2 120 157.6 262.6
4 11.2 27.4 34 31.7 60.5 125 169.0 280.7
5 11.8 28.3 35 32.6 61.9 130 181.0 299.3
6 12.3 29.2 36 33.4 63.3 135 193.5 319.6
7 12.9 30.1 37 34.3 64.6 140 206.6 341.3
8 13.5 31.0 38 35.2 66.1 145 220.3 364.0
9 14.0 32.0 39 36.1 67.5 150 234.6 387.2
10 14.6 32.9 40 37.0 69.0 155 249.5 410.8
11 15.2 33.9 41 37.9 70.5 160 265.1 434.6
42 38.8 72.0
To use the charts, just choose a temperature from the left column of one of the charts and go to the right across to either refrigerant 12 (like refrigerators) or refrigerant 22 (like most home air conditioning) and see what the pressure will be if it is in a sealed container or system at that exact temperature and is not being pumped by the compressor.

Refrigerant 22 at 140 (as would be a can of it sitting outside in the sun) would have a pressure inside the can of 341.3 pounds.

You can also select a pressure from one of the columns such as R-22 down the third chart to find the pressure of 341.3 pounds and see what the ambient (air around the can) temperature is at that pressure.

These pressure temperature charts are important for many reasons, but an easy example would be to see what the temperature of the refrigerant is inside the evaporator if the suction pressure is, say, 70 pounds and your pressure gauge doesn't show this temperature/pressure conversion. Look at the chart under R-22 and down to the pressure of 70 pounds and see that the temperature of the refrigerant inside the cooling coil is 41 degrees. Isn't this convenient?

See also:

Refrigerant 22, 123, 134a, 404A, 410A, & 507 .pdf Chart by DuPont®

Honeywell's R-22 Allocation Brochure of 06/03 #G-525-109

Honeywell Refrigerants
P.O.Box 1053
Morristown, NJ 07962-1053

What is the R-22 Allocation?

In January of 2003 the United States Environmental Protection
Agency (EPA) published a regulation that limited the amount
of virgin R-22 and R-142b refrigerants that can be made or
imported into the USA.

Before 2003, any company could make, import, or sell
refrigerant R-22 (also known as HCFC-22).  With this new
regulation, only twenty-five companies were granted limited
"rights" to manufacture or import R-22 into the U.S. for use in
systems where the chemical could be released to the
environment.  Refrigerant manufacturers and importers may not
produce or import more of these chemicals for which they
have "rights."

The regulation covers not only the 50 U.S. states, but territories
and provinces such as Puerto Rico, Guam and the U.S. Virgin
Islands.  This regulation was published in the U.S. Federal
Register as the "Allowance System for Controlling HCFC
Production, Import and Export; Final Rule" on January 21, 2003
("Allocation Regulation")

This regulation will affect R-22 and R-142b, and refrigerant
blends that contain them.  This includes R-401A (MP39),
R-401B (MP66), R-402A (HP80), R-402B (HP81), R-408A,
R-409A, R414A, R-414B, R-416A, R-420A and others.  The fine
for the illegal importation of R-22 can be up to $12,474 per
pound.

Why did the EPA do this?

In order to make sure that the United States would comply with
the Montreal Protocol on Substances that Deplete the Ozone
Layer ("Montreal Protocol"), the U.S. Congress passed the 1990
Clean Air Act that ordered the EPA to enact regulations to
phase out R-22 and other ozone-depleting chemicals.  Initially,
this included phasing out chlorofluorocarbons (CFCs) which
were quickly banned by the mid 1990's.  Now the EPA must
begin the phaseout of hydrochlorofluorocarbons (HCFCs) and it
has chosen to begin this process by completely phasing out the
most harmful chemical (HCFC-141b) used in foam insulation,
and by limiting the production and import of moderately
ozone-depleting chemicals HCFC-22 and HCFC-142b.

This 2003 action by the EPA will allow the U.S. to meet the
35% reduction in HCFC consumption required by 2004.

What other regulations are coming?


2004 Beijing Amendment Ratification

As part of the Allocation Regulation, the EPA is expected to ban
buying and selling of controlled HCFCs with certain countries
unless those countries ratify the Beijing Amendment to the
Montreal Protocol.  This amendment requires countries that
manufacture HCFCs to agree to limits on the amounts of HCFC
chemicals that they produce.  Currently, this list includes Mexico
and China.  These countries represent a meaningful amount of
the R-22 imported into the U.S. in recent years.

2006 DOE Regulations

Due to Department of Energy regulations passed in 2002, the
minimum efficiency of most new residential air conditioners is
being raised from 10 SEER to 12 SEER after 2005.  This will
likely require air-conditioning manufacturers to use
15%-25% more R-22 refrigerant in new equipment.  This will
increase demand for R-22 for installing and servicing
these systems.

2009 Expiration of Allocations

The R-22 allocations granted by the EPA expire in 2009, and the
EPA has not yet passed any regulations that would allow for
R-22 to be made or imported after 2009.  The EPA has stated
that it intends to pass additional regulations that will allow for
continued production and use of R-22 as service refrigerant
after 2009, however it is expected that these regulations will
reduce the R-22 allocations that it granted in 2003 and disallow
the production or importation of R-22 for use in any new
equipment after 2009.

2015 Reductions

Some dealers wrongly believe that R-22 for servicing existing
systems will not be affected until 2020.  Actually, the EPA is
required to implement additional regulations to reduce the limit
on consumption of ozone-depleting HCFCs such as R-22 by
90% after 2014.

Although the U.S. demand for R-22 for servicing existing
systems is likely to decrease by that date, the available HCFC
allocation will have to be used to supply refrigerants (R-22,
R-124, R-142b, MP39, MP66, HP80, and others) and solvents
(HCFC-225ca, HCFC-225cb).

Most new air conditioning and refrigeration equipment being
installed today is expected to still be in service in 2015, so
building owners and consumers need to take into consideration
the potential for future shortages of HCFC products when
considering installing new R-22 or other HCFC-based
equipment.  This is particularly important if systems sold today
are covered by warranties or service contracts.

Although regulations allow for continued production of
R-22 for service through 2019, there is no guarantee that
the quantities that will be produced or made available will
be sufficient to meet U.S. market demand.  Individuals and
companies who make claims guaranteeing sufficient
supply of HCFC-22 until 2020 do so at their own risk

What is replacing R-22?

There are 4 non-ozone depleting refrigerants that are
widely recommended by equipment and compressor
manufacturers to replace R-22.

R-404A and R-507

These products are viery similar, and are already widely used in low and
medium-temperature refrigeration systems.  R-507 is a true azeotrope
and slightly more efficient than R-404A, but R-404A is used more
broadly in both small hermetic and large commercial systems.

R-407C

This refrigerant is extensively used in Europe and Japan where R-22 is
already phased out in many types of equipment, and is an excellent per-
formance match to R-22 allowing it to be used in R-22 air conditioning
and refrigeration systems without significant equipment changes.

R410A

This refrigerant is now used in new air-conditioning equipment from
nearly every major equipment manufacturer in the world, and offers
significant performance advantages over R-22.   R410A offers improved
pressure-drop characteristics that allow for improved system efficiency
over R-22.  It is a near-azeotrope with the lowest glide of any 400-series
refrigerant, allowing for easy handling and near-zero change in
composition in cases of major leaks.

Many negative myths about R-410A have been circulated by people who
have never used R-410A or installed R-410A equipment.  This includes
inflated fears about R-410A pressures and synthetic lubricants.  For more
information on what consumers and customers are hearing about
R-410A, dealers are invited to visit www.410A.com.

What about Reclaimed R-22?

According to the most recent information available on the EPA's
website the total amount of R-22 refrigerant reclaimed in the
U.S. in 2000 was 7.1 million pounds.  Putting this in perspective,
the total annual U.S. consumption allocations assigned by the
EPA were for more than 250 million pounds of R-22 annually.
Although reclamation is both mandatory and an important
source for service refrigerant, it is unlikely to meet a
significant part of market demand unless recovery and
reclamation of R-22 substantially increases.

What about R-22 Drop-Ins?

The idea of a "drop-in" replacement where no oil change is
needed to replace R-22 is a popular one among air-conditioning
dealers.  Unfortunately, the hype around R-22 "drop-ins" is quite
different from the reality.

Using any HFC refrigerant in an R-22 system without replacing
some or all of the mineral oil with a lubricant that is more
compatible with HFCs will result in a decrease in the rate of oil
return to the compressor, potentially to the point of compressor
burnout or early failure.  This includes HFC refrigerants that use
small amounts of hydrocarbons, alcohols, or even magical
"pixi-dust" to increase miscibility with mineral oil.  This reduced
oil return reduces the long-term reliability of a system, a key
reason why the use of these refrigerants as "drop-ins" will typi-
cally invalidate warranties on new or replacement equipment.

Additionally, R-22 "drop-in" or "direct" replacements typically
have lower efficiency and capacity than R-22.  In commercial and
industrial R-22 systems where food is manufactured,
transported or stored, this loss of capacity may result in slowed
production or unpredictable temperature variations outside of
FDA-mandated ranges.

For new equipment, R-22 "direct" or "drop-in" replacements
present additional cost, handling, and reliability problems.
As a result, air-conditioning and refrigeration equipment
manufacturers have almost universally selected a combination
of synthetic lubricants and HFC refrigerants such as R-410A to
provide adequate energy efficiency, long-term reliability, and
cost effectiveness.

What Should I do Now?

1)  Communicate to your customers that R-22 is now a
      regulated and controlled product, with limited supply
    and future regulations likely to impact availability and
    prices.  This could also affect refrigerants that contain R-22
    or R-142b, including many R-12 and R-502 replacement
    blends.

2)  Communicate to your customers how the U.S.
    air-conditioning and refrigeration industry is migrating
    from R-22 to non-ozone depleting products.  By installing
    new systems that use non-ozone depleting refrigerants,
    like R-410A the industry will allow for more R-22 to be
    available to service existing systems, and reduce the
      likelihood of R-22 shortages.

3)  If you sell or service air-conditioning systems, learn more
    about R-410A, including how to communicate the
      advantages of R-410A equipment to your customers.
    Becoming a leader in R-410A today can give you an
    advantage over your competitors.  Visit www.410A.com.

4)  If you service or specify refrigerants for commercial
     refrigeration systems, reduce the risks and costs for
       your customers by recommending OEM-approved and
       environmentally safer Genetron Refrigerants¹.

-------------------------------------------
¹ Genetron® is a registered trademark of Honeywell. Copyright 2003 Honeywell. All rights reserved. For additional Information we invite you to consult your Genetron® refrigerant wholesaler and visit www.genetron.com.
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